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2017 Waec Chemistry Questions And Answers – May/June Expo


CHEMISTRY ANSWERS 

NOTE THAT ^ means Raise to Power


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CHEMISTRY OBJ.

1DCDBCBDBCA

11DBAADCDBCB

21DBCBCCDBAD

31BACBACBCCD

41BDACABDABD===============


 1 ai )

an acid base indicator is a weak acid or weak base that exhibits a colour change as the concentration of hydrogen (H ^ + ) or hydroxide ( H^ - ) ions changes in an aqueous solution

1 aii )

methyl- orange

1 b )

i) oxidizing agent

ii )mixed anhydride

1 c )

enthalpy of combustion is the heat evolved when one mole of a substance is completely burns in oxygen gas under standard conditions

1 cii )

enthapy of combustion is always negetive since it involvs a rise in temperature and heat of reactants is greater than the heat of products

1 d )

primary cell is a cell that cannot be re charged while secondary cell is a cell that can be recharged

1 dii )

primary cell - - daniell cell

secondary cell -- lead accumulator

1 e )

mole is the unit of measurement in the International System of Units (SI ) for amount of substance. The unit is defined as the amount of a chemical substance which contains as many representative particles , e .g ., atoms , molecules , ions , electrons, or photons , as there are atoms in 12 grams of carbon -12 ( 12C) , the isotope of carbon with relative atomic mass

1 f )

n = V=40 cm^ 3

c = 0. 40moldm^ 3

n = cv / 1000

0 .40*40/ 1000 = 0. 016mol .




1 g )

i) Platinum

ii ) Carbon

1 h )

i) Hydrogen bonds

ii ) Vander waals forces

1 i) Water( H2 O) and Carbonmonoxide ( Co)

1 j) 1 s^ 2 2 s^ 2 2 p ^ 6 3s ^ 2 3p ^ 6 3 d ^ 3 4s ^ 2

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(2a)

i)periodic law states that properties of elements are the periodic function of their atomic number

ii)periodic property of element is the variation of the properties of element in a regular pattern both down the group and acrose the period

2aii)

i)ionization energy

ii)electron affinity

iii)electropositivity

2aiii)

ionization energy increase from left to right acrose a period because the nuclear charge increase progressively while the screening effect remain constant

-atomic reduis decreases from left to right acrose the period because nuclear charge effect out weighs screening effect,which remains constant because the number of shell in a period is constant 

-electron affinity increase from left to right across a period because an additional electron will experience a greater repulsion than altraction from the positively charged nucleus

2b)

the relative atomic mass of an element is the mass of one atom of the element compared with the mass of an atom of the carbon -12 isotope whos mass is exactly 12

2bci)

isotopy

2cii)

the isotopes have difference number of neutron

2ciii)

R.A.M=(75/100*35)+(25/100*37)

=2634.25

2di)

I CO2 by downward delivery

II HCL by downward delivery

III H2 by upward delivery

2dii)

I because it is denser than air

II because it is denser than air





3ai)

Thermal cracking

3aii)

C4H8

3aiii)

(I) H H. H

| | |

H-C-C-C=C

| | | |

H H H H

and

(II) H H

| |

H-C-C=C-C-H

| | | |

H H H H

3aiv)

I-normal butene

II -But-2-ene

Ni

3av)

C4H8 +H2 -------> C4H10

250c

3b)

method

- rub the fat on a blank white paper

- pour Sudan (III) dye over the paper

-wash the paper under tap

Observation

- rubbing the fat on the paper produces a translucent color

-pouring sudan (III) will stain the blot red

Conclusion

- fat is present because sudan (III) can stain fat red

 

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5ai) worm the unknown substance with concentrated H2SO4 in a test tube. if trioxonitrate(v) ion's are/is present, some trioxonitrate(v) acid will be condensed as oily drops on the upper part of the tube. On further heating, the acid decomposes yielding brown fums of NO2 gas.


5iia) Sodium chloride is used for:

=preserving food

=glazing pottery


5iib) Sodium trioxocarbonate(iv) is used for:

=standardizing acids in the laboratory

=the manufacture of glass




 5bi) 

C(s) + O2(g) =====> Co2(g)

Co2(g) + C(s) =====> 2Co(g)

Fe2O3(s) + 3Co(g) =====> 2Fe(l) + 3Co2(g)

The limestone present decomposes as follows:

CaCo3(s) =====> CaO(s) + Co2(g)

Which is available to remove silicon(iv) oxide impurity

SiO2(s) + CaO(s) =====> CaSiO3(s)


5bii) Faraday's first law of electrolysis states that, the mass (m) of an element discharged during an electrolysis is directly proportional to the quantity of electricity (Q) passing through it.

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